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Cadmium pollution from phosphate fertilizers in arable soils and crops: an overview

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《农业科学与工程前沿(英文)》 2019年 第6卷 第4期   页码 419-430 doi: 10.15302/J-FASE-2019273

摘要:

The application of mineral and organic phosphorus fertilizers to arable land has greatly increased crop yield to meet the world food demand. On the other hand, impurities in these fertilizers, such as heavy metals, are being added to agricultural soils, resulting both from the raw materials themselves and the processes used to obtain the final product. Cadmium, a non-essential and toxic heavy metal, has been found in relatively high amounts in common P fertilizers obtained from sediments. This metal poses a high risk for soil fertility, crop cultivation, and plants in general. Furthermore, human health might be compromised by the cadmium concentrations in agricultural and livestock products, due to the bioaccumulation effect in the food web. The accumulation in the different matrixes is the result of the high mobility and flexible availability of this harmful metal. This review summarizes risks to human health, the factors influencing cadmium movement in soils and crop uptake, as well as common plant responses to its toxicity. In addition, it summarizes cadmium balances in soils, trends, long-term experiments, and further studies. Cadmium inputs and outputs in arable soil, together with their calculated concentrations, are compared between two different regions: the European countries (in particular Germany) and China. The comparison appears useful because of the different proportions in the inputs and outputs of cadmium, and the diverse geographical, environmental and social factors. Moreover, these variables and their influences on cadmium contamination improve the understanding of the pollution from phosphate fertilizers and will help to establish future mitigation policies.

关键词: soil pollution     arable land     crop production     cadmium balance     P fertilizer     cadmium toxicity    

Polypropylene microplastics alter the cadmium adsorption capacity on different soil solid fractions

《环境科学与工程前沿(英文)》 2022年 第16卷 第1期   页码 3-3 doi: 10.1007/s11783-021-1437-z

摘要:

Microplastics (MPs) are widely present in a variety of environmental media and have attracted more and more attention worldwide. However, the effect of MPs on the interaction between heavy metals and soil, especially in soil solid fraction level, is not well understood. In this study, batch experiments were performed to investigate the adsorption characteristics of Cd in bulk soil and three soil solid fractions (i.e. particulate organo matter (POM), organic-mineral compounds (OMC), and mineral) with or without polypropylene (PP) MPs.

关键词: Polypropylene microplastics     Cadmium     Adsorption     POM     OMC     Mineral    

Identification of pakchoi cultivars with low cadmium accumulation and soil factors that affect theircadmium uptake and translocation

Lin WANG,Yingming XU,Yuebing SUN,Xuefeng LIANG,Dasong LIN

《环境科学与工程前沿(英文)》 2014年 第8卷 第6期   页码 877-887 doi: 10.1007/s11783-014-0676-7

摘要: The selection and use of low-Cd-accumulating cultivar (LCAC) has been proposed as one of the promising approaches in minimizing the entry of Cd in the human food chain. This study suggests a screening criterion of LCACs focusing on food safety. Pot culture and plot experiments were conducted to screen out LCACs from 35 pakchoi cultivars and to identify the crucial soil factors that affect Cd accumulation in LCACs. Results of the pot culture experiment showed that shoot Cd concentrations under the three Cd treatments significantly varied across cultivars. Two cultivars, Hualv 2 and Huajun 2, were identified as LCACs because their shoot Cd concentrations were lower than 0.2 mg·kg under low Cd treatment and high Cd exposure did not affect the biomass of their shoots. The plot experiment further confirmed the consistency and genotypic stability of the low-Cd-accumulating traits of the two LCACs under various soil conditions. Results also showed that soil phosphorus availability was the most important soil factor in the Cd accumulation of pakchoi, which related negatively not only to Cd uptake by root but also to Cd translocation from root to shoot. The total Cd accumulation and translocation rates were lower in the LCACs than in the high-Cd cultivar, suggesting that Cd accumulation in different cultivars is associated with the Cd uptake by root as well as translocation from root to shoot. This study proves the feasibility of the application of the LCAC strategy in pakchoi cultivation to cope with Cd contamination in agricultural soils.

关键词: pakchoi (Brassica chinensis L.)     cadmium contamination     low-cadmium-accumulating cultivar (LCAC)     genotype variation     soil factor     translocation    

The implications of planting mode on cadmium uptake and remobilization in rice: Field experiments across

《环境科学与工程前沿(英文)》 2021年 第15卷 第6期 doi: 10.1007/s11783-021-1431-5

摘要:

•Direct seeding (DS) method led to more distributed Cd in aerial parts of rice.

关键词: Cadmium     Genotypes     Growth stages     Micro X-ray fluorescence     Planting mode    

Cadmium tolerance and accumulation in fifteen wetland plant species from cadmium-polluted water in constructed

Jianguo LIU,Wen ZHANG,Peng QU,Mingxin WANG

《环境科学与工程前沿(英文)》 2016年 第10卷 第2期   页码 262-269 doi: 10.1007/s11783-014-0746-x

摘要: Variations in cadmium (Cd) tolerances and accumulations among fifteen wetland plant species in moderately (0.5 mg·L ) and heavily (1.0 mg·L ) Cd-polluted wastewaters were investigated in constructed wetlands. Cd removal efficiencies from the wastewaters were more than 90%, and 23.5% and 16.8% of the Cd in the water accumulated in wetland plants for 0.5 and 1.0 mg·L Cd treatments, respectively. The variations among the plant species were 29.4-fold to 48.7-fold in plant biomasses, 5.4-fold to 21.9-fold in Cd concentrations, and 13.8-fold to 29.6-fold in Cd accumulations. The plant species were also largely diversified in terms of Cd tolerance. Some species were tolerant of heavy Cd stress, and some others were sensitive to moderate Cd level. Four wetland plant species were selected for the treatment of Cd-polluted wastewater for their high Cd accumulating abilities and relative Cd tolerances. Plant Cd quantity accumulations are correlated positively and significantly ( <0.05) with plant biomasses and correlated positively but insignificantly ( >0.05) with plant Cd concentrations. The results indicate that the Cd accumulation abilities of wetland plant species are determined mainly by their biomasses and Cd tolerances in growth, which should be the first criteria in selecting wetland plant species for the treating Cd-polluted wastewaters. Cd concentration in the plants may be the second consideration.

关键词: cadmium (Cd)     wastewater treatment     wetland plant     selection     index    

Preparation of hapten-specific monoclonal antibody for cadmium and its ELISA application to aqueous samples

Huan HE, Bo TANG, Cheng SUN, Shaogui YANG, Weijuan ZHENG, Zichun HUA

《环境科学与工程前沿(英文)》 2011年 第5卷 第3期   页码 409-416 doi: 10.1007/s11783-011-0349-8

摘要: High-affinity and specific monoclonal antibodies against cadmium-ethylene diamine tetraacetic acid (EDTA) complex have been produced using the hybridoma technique. A hapten was synthesized and characterized by Fourier Transform Infrared Spectroscopy (FT-IR) and UV-Vis. Competitive enzyme-linked immunosorbent assay (ELISA) for quantitative detection of cadmium in aqueous sample was developed. The monoclonal antibody with high level of binding affinity for Cd-IEDTA-BSA and high specificity for soluble Cd-EDTA complex showed less than 0.99% cross-reactivity with other 11 metals. The limit of detection was 0.10 μg·L , and the effective linear range was 10 –10 μg·L . The intra- and inter-assay coefficient variations were 1.5%–6.3% and 3.2%–7.4%, respectively. The spike recovery in different water samples were between 98.5% and 110.3%. The detection limit of this assay was well below the allowable concentration of cadmium (3 μg·L ), and the working range was wider than that of other methods which showed the range of 2.19–86.38 and 0–10 μg·L . The competitive ELISA established in this paper was sensitive and accurate in the screening of cadmium in aqueous samples. The results will lay a solid foundation for construction of an immunoassay kit for cadmium.

关键词: cadmium     hapten     monoclonal antibody     enzyme-linked immunosorbent assay (ELISA)    

Simulation of bubble column reactors using CFD coupled with a population balance model

Tiefeng WANG

《化学科学与工程前沿(英文)》 2011年 第5卷 第2期   页码 162-172 doi: 10.1007/s11705-009-0267-5

摘要: Bubble columns are widely used in chemical and biochemical processes due to their excellent mass and heat transfer characteristics and simple construction. However, their fundamental hydrodynamic behaviors, which are essential for reactor scale-up and design, are still not fully understood. To develop design tools for engineering purposes, much research has been carried out in the area of computational fluid dynamics (CFD) modeling and simulation of gas-liquid flows. Due to the importance of the bubble behavior, the bubble size distribution must be considered in the CFD models. The population balance model (PBM) is an effective approach to predict the bubble size distribution, and great efforts have been made in recent years to couple the PBM into CFD simulations. This article gives a selective review of the modeling and simulation of bubble column reactors using CFD coupled with PBM. Bubble breakup and coalescence models due to different mechanisms are discussed. It is shown that the CFD-PBM coupled model with proper bubble breakup and coalescence models and interphase force formulations has the ability of predicting the complex hydrodynamics in different flow regimes and, thus, provides a unified description of both the homogeneous and heterogeneous regimes. Further study is needed to improve the models of bubble coalescence and breakup, turbulence modification in high gas holdup, and interphase forces of bubble swarms.

关键词: bubble column     computational fluid dynamics     bubble breakup and coalescence     population balance model     bubble size distribution    

Gut microbial balance and liver transplantation: alteration, management, and prediction

null

《医学前沿(英文)》 2018年 第12卷 第2期   页码 123-129 doi: 10.1007/s11684-017-0563-2

摘要:

Liver transplantation is a conventional treatment for terminal stage liver diseases. However, several complications still hinder the survival rate. Intestinal barrier destruction is widely observed among patients receiving liver transplant and suffering from ischemia–reperfusion or rejection injuries because of the relationship between the intestine and the liver, both in anatomy and function. Importantly, the resulting alteration of gut microbiota aggravates graft dysfunctions during the process. This article reviews the research progress for gut microbial alterations and liver transplantation. Especially, this work also evaluates research on the management of gut microbial alteration and the prediction of possible injuries utilizing microbial alteration during liver transplantation. In addition, we propose possible directions for research on gut microbial alteration during liver transplantation and offer a hypothesis on the utilization of microbial alteration in liver transplantation. The aim is not only to predict perioperative injuries but also to function as a method of treatment or even inhibit the rejection of liver transplantation.

关键词: gut microbial balance     liver transplantation     ischemia–reperfusion     acute rejection    

Nonlinear sealing force of a seawater balance valve used in an 11000-meter manned submersible

《机械工程前沿(英文)》 2023年 第18卷 第1期 doi: 10.1007/s11465-022-0726-y

摘要: Balance valve is a core component of the 11000-meter manned submersible “struggle,” and its sealing performance is crucial and challenging when the maximum pressure difference is 118 MPa. The increasing sealing force improves the sealing performance and increases the system’s energy consumption at the same time. A hybrid analytical–numerical–experimental (ANE) model is proposed to obtain the minimum sealing force, ensuring no leakage at the valve port and reducing energy consumption as much as possible. The effects of roundness error, environmental pressure, and materials on the minimum sealing force are considered in the ANE model. The basic form of minimum sealing force equations is established, and the remaining unknown coefficients of the equations are obtained by the finite element method (FEM). The accuracy of the equation is evaluated by comparing the independent FEM data to the equation data. Results of the comparison show good agreement, and the difference between the independent FEM data and equation data is within 3% when the environmental pressure is 0–118 MPa. Finally, the minimum sealing force equation is applied in a balance valve to be experimented using a deep-sea simulation device. The balance valve designed through the minimum sealing force equation is leak-free in the experiment. Thus, the minimum sealing force equation is suitable for the ultrahigh pressure balance valve and has guiding significance for evaluating the sealing performance of ultrahigh pressure balance valves.

关键词: seawater balance valve     sealing performance     hybrid ANE model     FEM     minimum sealing force equation    

Quantitative analysis of yield and soil water balance for summer maize on the piedmont of the North China

Jingjing WANG,Feng HUANG,Baoguo LI

《农业科学与工程前沿(英文)》 2015年 第2卷 第4期   页码 295-310 doi: 10.15302/J-FASE-2015074

摘要: The North China Plain (NCP) is a major grain production area in China, but the current winter wheat-summer maize system has resulted in a large water deficit. This water-shortage necessitates the improvement of crop water productivity in the NCP. A crop water model, AquaCrop, was adopted to investigate yield and water productivity (WP) for rain-fed summer maize on the piedmont of the NCP. The data sets to calibrate and validate the model were obtained from a 3-year (2011–2013) field experiment conducted on the Yanshan piedmont of the NCP. The range of root mean square error (RMSE) between the simulated and measured biomass was 0.67–1.25 t·hm , and that of relative error (RE) was 9.4%–15.4%, the coefficient of determination ( ) ranged from 0.992 to 0.994. The RMSE between the simulated and measured soil water storage at depth of 0–100 cm ranged from 4.09 to 4.39 mm; and RE and in the range of 1.07%–1.20% and 0.880–0.997, respectively. The WP as measured by crop yield per unit evapotranspiration was 2.50–2.66 kg·m . The simulated impact of long-term climate (i.e., 1980–2010) and groundwater depth on crop yield and WP revealed that the higher yield and WP could be obtained in dry years in areas with capillary recharge from groundwater, and much lower values elsewhere. The simulation also suggested that supplementary irrigation in areas without capillary groundwater would not result in groundwater over-tapping since the precipitation can meet the water required by both maize and ecosystem, thus a beneficial outcome for both food and ecosystem security can be assured.

关键词: AquaCrop     summer maize     soil water balance     water productivity    

Genotype variations in accumulation of cadmium and lead in celery (

Kun ZHANG, Jianbing WANG, Zhongyi YANG, Guorong XIN, Jiangang YUAN, Junliang XIN, Charlie HUANG

《环境科学与工程前沿(英文)》 2013年 第7卷 第1期   页码 85-96 doi: 10.1007/s11783-012-0399-3

摘要: To help reduce risks of heavy metal pollution, two pot experiments were conducted to investigate the variations, transfer potential, and stability of Cadmium (Cd) and Lead (Pb) accumulations in celery ( L.) and to screen for low Cd and Pb accumulative cultivars. The maximum differences in shoot Cd concentration were 4.7-fold under low-Cd exposure and 3.3-fold under high-Cd exposure. These genotype variations in Cd accumulation are sufficiently large to help reduce Cd contamination risk in soil by using the Low-Cd-Accumulative genotypes. Cd accumulation of the Low-Cd-Accumulative genotypes is significantly positive correlated with Pb accumulation. Evidence obtained proves that Cd and Pb accumulations in celery are stable and genotype-dependent at the cultivar level. The presence of high-Pb contamination in soil promoted Cd accumulation in shoots of celery. Celery is considered a species with high risks in Cd pollution and low risks in Pb pollution. Among the tested cultivars, cv. Shuanggangkangbing (SGKB) had the lowest shoot Cd and Pb accumulating abilities, and thus is the most important material for breeding of pollution-safe cultivars (PSCs) to minimize Cd and Pb accumulations in celery.

关键词: cadmium (Cd) accumulation     lead (Pb) accumulation     celery     genotype variation     food safety    

Mass and heat balance calculations and economic evaluation of an innovative biomass pyrolysis project

Quanyuan WEI, Yongshui QU, Tianwei TAN

《化学科学与工程前沿(英文)》 2011年 第5卷 第3期   页码 355-361 doi: 10.1007/s11705-010-0567-9

摘要: Biomass can be converted into flammable gas, charcoal, wood vinegar, wood tar oil and noncombustible materials with thermo-chemical pyrolysis reactions. Many factors influence these processes, such as the properties of the raw materials, and temperature control and these will affect the products that are produced. Based on the data from a straw pyrolysis demonstration project, the mass and heat balance of the biomass pyrolysis process were analyzed. The statistical product and service solutions (SPSS) statistical method was used to analyze the data which were monitored on-site. A cost-benefit analysis was then used to study the viability of commercializing the project. The analysis included net present value, internal rate of return and investment payback period. These results showed that the straw pyrolysis project has little risk, and will produce remarkable economic benefits.

关键词: mass balance     heat balance     biomass pyrolysis     economic benefit    

Effects of rape straw and red mud on extractability and bioavailability of cadmium in a calcareous soil

Junxing YANG,Liqun WANG,Jumei LI,Dongpu WEI,Shibao CHEN,Qingjun GUO,Yibing MA

《环境科学与工程前沿(英文)》 2015年 第9卷 第3期   页码 419-428 doi: 10.1007/s11783-014-0674-9

摘要: Screening of cost-effective soil amendments is important to develop “ ” remediation techniques for cadmium (Cd) contaminated soils. In this study, different soil amendments, including red mud, a by-product of the alumina industry, and acid-treated, nano-treated by nano-particle milling, nano and acid-treated red muds, zeolite, corn straw, and rape straw, were evaluated to immobilize Cd in two added levels (2 and 5 mg Cd·kg soil) in a calcareous soil by single and sequential extractions and by cucumber ( L.) pot experiments. Results indicated that cruciferous rape straw significantly decreased the concentrations of water soluble, extractable Cd in soils, and Cd in cucumber plants, and it was more effective than gramineous corn straw. Also, red mud generally decreased the extractability and bioavailability of Cd added to calcareous soils more effectively than zeolite. Furthermore, the efficiency of red mud could be increased by the treatment of nano-particle milling due to the increase in specific surface area of red mud. It is potential to use rape straw and red mud as soil amendments to develop a cost-effective and efficient “ ” remediation technology for Cd mildly contaminated calcareous soils.

关键词: red mud     rape straw     cadmium     immobilization     calcareous soil    

Comparisons in subcellular and biochemical behaviors of cadmium between low-Cd and high-Cd accumulation

Meng XUE, Yihui ZHOU, Zhongyi YANG, Biyun LIN, Jiangang YUAN, Shanshan WU

《环境科学与工程前沿(英文)》 2014年 第8卷 第2期   页码 226-238 doi: 10.1007/s11783-013-0582-4

摘要: Subcellular distributions and chemical forms of cadmium (Cd) in the leaves, stems and roots were investigated in low-Cd accumulation cultivars and high-Cd accumulation cultivars of pakchoi ( L.). Root cell wall played a key role in limiting soil Cd from entering the protoplast, especially in the low-Cd cultivars. The high-Cd cultivars had significantly higher leaf and stem Cd concentrations than the low-Cd cultivars in cell wall fraction, chloroplast/trophoplast fraction, organelle fraction and soluble fraction. In low-Cd cultivars, which were more sensitive and thus had greater physiological needs of Cd detoxification than high-Cd cultivars, leaf vacuole sequestrated higher proportions of Cd. Cd in the form of pectate/protein complexes (extracted by 1 mol·L NaCl) played a decisive role in Cd translocation from root to shoot, which might be one of the mechanisms that led to the differences in shoot Cd accumulation between the two types of cultivars. Furthermore, the formation of Cd-phosphate complexes (extracted by 2% HAc) was also involved in Cd detoxification within the roots of pakchoi under high Cd stress, suggesting that the mechanisms of Cd detoxification might be different between low- and high-Cd cultivars.

关键词: cadmium (Cd)     low-Cd cultivar     pakchoi (Brassica chinensis L.)     subcellular distribution     chemical forms    

Single and joint effects of HHCB and cadmium on zebrafish (

Lei ZHANG, Jing AN, Qixing ZHOU

《环境科学与工程前沿(英文)》 2012年 第6卷 第3期   页码 360-372 doi: 10.1007/s11783-011-0353-z

摘要: As an important type of emerging pollutants, ecological toxicity and risk of artificial musks are increasingly concerned. Thus, single and joint toxic effects of 1,3,4,6,7,8-hexahydro-4,6,6,7,8,8- hexamethylcyclopenta-gamma-2-benzopyran (HHCB) as one of the most widely applied artificial musks and cadmium (Cd) as an toxic metal on zebrafish ( ) were investigated by the exposure of zebrafish to various concentrations of HHCB or/and Cd in feculent water containing bedloads. The results indicated that the joint effect of HHCB and Cd changed during different exposure times within 120 h. The index of the antioxidant enzyme system including superoxide dismutase (SOD) and peroxidase (POD), and malondialdehyde (MDA) were sensitive and induced in the zebrafish stressed by Cd, and content of soluble protein (SP) was sensitive to HHCB and could be used as a biomarker for HHCB. Joint effects on antioxidant enzymes depended more on the effect of single Cd in the first one or two days. However, in the rest exposure days, the effect of HHCB began to dominate in the joint effect during the exposure process.

关键词: 1     3     4     6     7     8-hexahydro-4     6     6     7     8     8-hexamethylcyclopenta-gamma-2-benzopyran (HHCB)     cadmium (Cd)     antioxidant biomarker     feculent water containing bedloads    

标题 作者 时间 类型 操作

Cadmium pollution from phosphate fertilizers in arable soils and crops: an overview

null

期刊论文

Polypropylene microplastics alter the cadmium adsorption capacity on different soil solid fractions

期刊论文

Identification of pakchoi cultivars with low cadmium accumulation and soil factors that affect theircadmium uptake and translocation

Lin WANG,Yingming XU,Yuebing SUN,Xuefeng LIANG,Dasong LIN

期刊论文

The implications of planting mode on cadmium uptake and remobilization in rice: Field experiments across

期刊论文

Cadmium tolerance and accumulation in fifteen wetland plant species from cadmium-polluted water in constructed

Jianguo LIU,Wen ZHANG,Peng QU,Mingxin WANG

期刊论文

Preparation of hapten-specific monoclonal antibody for cadmium and its ELISA application to aqueous samples

Huan HE, Bo TANG, Cheng SUN, Shaogui YANG, Weijuan ZHENG, Zichun HUA

期刊论文

Simulation of bubble column reactors using CFD coupled with a population balance model

Tiefeng WANG

期刊论文

Gut microbial balance and liver transplantation: alteration, management, and prediction

null

期刊论文

Nonlinear sealing force of a seawater balance valve used in an 11000-meter manned submersible

期刊论文

Quantitative analysis of yield and soil water balance for summer maize on the piedmont of the North China

Jingjing WANG,Feng HUANG,Baoguo LI

期刊论文

Genotype variations in accumulation of cadmium and lead in celery (

Kun ZHANG, Jianbing WANG, Zhongyi YANG, Guorong XIN, Jiangang YUAN, Junliang XIN, Charlie HUANG

期刊论文

Mass and heat balance calculations and economic evaluation of an innovative biomass pyrolysis project

Quanyuan WEI, Yongshui QU, Tianwei TAN

期刊论文

Effects of rape straw and red mud on extractability and bioavailability of cadmium in a calcareous soil

Junxing YANG,Liqun WANG,Jumei LI,Dongpu WEI,Shibao CHEN,Qingjun GUO,Yibing MA

期刊论文

Comparisons in subcellular and biochemical behaviors of cadmium between low-Cd and high-Cd accumulation

Meng XUE, Yihui ZHOU, Zhongyi YANG, Biyun LIN, Jiangang YUAN, Shanshan WU

期刊论文

Single and joint effects of HHCB and cadmium on zebrafish (

Lei ZHANG, Jing AN, Qixing ZHOU

期刊论文